Facile synthesis of supported CuNi nano-clusters as an electrochemical CO2 reduction catalyst with broad potential range

Literature Information

Publication Date 2023-10-16
DOI 10.1039/D3CC03758D
Impact Factor 6.222
Authors

Jiale Wang, Fan Li, Runhua Li, Qian Xiang, Wencong Zhang, Chengyi Song, Peng Tao, Wen Shang


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Abstract

A nitrogen-doped carbon-supported CuNi bimetallic nanocluster catalyst (CuNi–NC) was first synthesized via a facile ZIF-derived method. With a synergistic effect between Cu and Ni, the catalyst exhibited a maximum FECO of 96.3%. FECO is higher than 90% in a broad potential range of 600 mV, which was ascribed to the controllable pore size distribution. Density functional theory further demonstrated the preferred formation of *COOH in the catalytic process.

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