Visible-light driven electron–donor–acceptor (EDA) complex-initiated synthesis of thio-functionalized pyridines

Literature Information

Publication Date 2023-05-12
DOI 10.1039/D3CC01678A
Impact Factor 6.222
Authors

Hirendra Nath Dhara, Amitava Rakshit, Dinabandhu Barik, Koustuv Ghosh, Bhisma K. Patel


View Original

Abstract

A visible/solar-light-induced electron–donor–acceptor (EDA)-aggregated/mediated radical cyclization between (E)-2-(1,3-diarylallylidene)malononitriles and thiophenols leads to poly-functionalized pyridines. The two reacting partners form an EDA complex that absorbs light and triggers the single-electron transfer (SET) to generate a thiol radical, which undergoes addition/cyclization with dicyanodiene through the formation of C–S and C–N bonds.

Related Literature

A neutral self-assembled coordination cage organized for inclusion of aromatic guests

Amir H. Mahmoudkhani, Adrien P. Côté, George K. H. Shimizu

2004-10-15 Communication

DOI: 10.1039/B412325E

Synthesis and characterization of a benzene-centered, phthalocyanine hexamer

Giovanni Bottari, Tomás Torres

2004-10-14 Communication

DOI: 10.1039/B411960F

Highly enantioselective hydrolysis of alicyclic meso-epoxides with a bacterial epoxide hydrolase from Sphingomonas sp. HXN-200: simple syntheses of alicyclic vicinal trans-diols

Dongliang Chang, Zunsheng Wang, Maarten F. Heringa, Renato Wirthner, Bernard Witholt, Zhi Li

2003-03-18 Communication

DOI: 10.1039/B300435J

Water-soluble supramolecular bowls formed by intra-clipping of resorcin[4]arene-based ligands with Pd(ii) ions

Seong Jin Park, Dong Mok Shin, Shigeru Sakamoto, Kentaro Yamaguchi, Young Keun Chung, Myoung Soo Lah

2003-03-19 Communication

DOI: 10.1039/B212855A

Fabrication of nanowires with polymer shells using treated carbon nanotube bundles as macro-initiators

Yuyang Liu, Jing Tang, J. H. Xin

2004-10-26 Communication

DOI: 10.1039/B412282H

Cyclodehydrogenation of di- and tetra(benzimidazol-2-yl)benzenes to give model heteroaromatic discotic systems

Weicheng Wu, Andrew. C. Grimsdale, Klaus Müllen

2003-04-07 Communication

DOI: 10.1039/B301512M

Selective growth of a less stable polymorph of 2-iodo-4-nitroaniline on a self-assembled monolayer template

Rupa Hiremath, Stephen W. Varney, Jennifer A. Swift

2004-10-15 Communication

DOI: 10.1039/B411649F

Highly substituted pyridinesvia tethered imine–enamine (TIE) methodology

Steven A. Raw, Richard J. K. Taylor

2004-01-27 Communication

DOI: 10.1039/B316107B

Monitoring the formation of biosilica catalysed by histidine-tagged silicatein

Muhammad Nawaz Tahir, Patrick Théato, Werner E. G. Müller, Heinz C. Schröder, Andreas Janshoff, Jian Zhang, Joachim Huth, Wolfgang Tremel

2004-10-27 Communication

DOI: 10.1039/B410283E

Controlled assembly of luminescent racks based on heteroleptic dinuclear lanthanide complexes

M. Margarita Castaño-Briones, Andrew P. Bassett, Linette L. Meason, Peter R. Ashton, Zoe Pikramenou

2004-10-26 Communication

DOI: 10.1039/B412999G

You might also like

Compound Q&A

What industries use (1R,3S)-1,3-Cyclopentanediol (CAS: 16326-97-9)?

(1R,3S)-1,3-Cyclopentanediol finds applications in various industries. In the ph...

16326-97-9(1R,3S)-1,3-Cyclopen...
Compound Q&A

What precautions should be taken when handling N'-[4-(Dimethylamino)phenyl]-N,N-dimethyl-1,4-benzenediamine (CAS: 637-31-0)?

When handling N'-[4-(Dimethylamino)phenyl]-N,N-dimethyl-1,4-benzenediamine, it i...

637-31-0N'-[4-(Dimethylamino...
Compound Q&A

Are there alternatives to 5-(2,4-Difluorophenyl)-2-methoxypyrimidine (CAS: 1352318-16-1) in synthesis?

There are several alternatives to 5-(2,4-Difluorophenyl)-2-methoxypyrimidine in ...

1352318-16-15-(2,4-Difluoropheny...
Compound Q&A

What regulatory guidelines apply to 1-(3-Methoxyphenoxy)propan-2-ol (CAS: 382141-68-6)?

1-(3-Methoxyphenoxy)propan-2-ol (CAS: 382141-68-6) must comply with the Globally...

382141-68-61-(3-Methoxyphenoxy)...
Compound Q&A

Is Tetrodotoxin Citrate (CAS: 18660-81-6) safe?

Tetrodotoxin Citrate is extremely dangerous and should be handled with extreme c...

18660-81-6Tetrodotoxin Citrate
Compound Q&A

What are the main uses of 2-Methyl-2-propanyl [(1R,3S)-3-hydroxycyclopentyl]carbamate (CAS: 225641-84-9)?

2-Methyl-2-propanyl [(1R,3S)-3-hydroxycyclopentyl]carbamate (CAS: 225641-84-9) i...

225641-84-92-Methyl-2-propanyl ...
Compound Q&A

How should waste containing 4-(2-Hydroxyhexafluoroisopropyl)Benzoic Acid (CAS: 16261-80-6) be handled?

Waste containing 4-(2-Hydroxyhexafluoroisopropyl)Benzoic Acid (CAS: 16261-80-6) ...

16261-80-64-(2-Hydroxyhexafluo...
Compound Q&A

How is 2-Methyl-2-proanyl {(2S)-1-[(benzyloxy)amino]-3-hydroxy-3-methyl-1-oxo-2-butanyl}carbamate (CAS: 102507-19-7) typically synthesized?

2-Methyl-2-proanyl {(2S)-1-[(benzyloxy)amino]-3-hydroxy-3-methyl-1-oxo-2-butanyl...

102507-19-72-Methyl-2-propanyl ...
Compound Q&A

What is Benzeneethanamine, α-ethyl-, hydrochloride (1:1) (CAS: 20735-15-3)?

Benzeneethanamine, α-ethyl-, hydrochloride (1:1) is an organic compound with the...

20735-15-3Benzeneethanamine, α...
Compound Q&A

Are there alternatives to 3-{(E)-[4-(Dimethylamino)phenyl]diazenyl}benzoic acid (CAS: 20691-84-3) in synthesis?

In the synthesis of compounds similar to 3-{(E)-[4-(Dimethylamino)phenyl]diazeny...

20691-84-33-{(E)-[4-(Dimethyla...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.