Water-soluble supramolecular bowls formed by intra-clipping of resorcin[4]arene-based ligands with Pd(ii) ions
Literature Information
Seong Jin Park, Dong Mok Shin, Shigeru Sakamoto, Kentaro Yamaguchi, Young Keun Chung, Myoung Soo Lah
Bowl-shaped superstructures have been constructed by intra-clipping of resorcin[4]arene derivatives with two equivalents of (en)Pd(NO3)2 in water. The binding phenomena of the aromatic carboxylates were proven to be both enthalpically and entropically favoured.
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