Disturbance of intermolecular forces: eutectics as a new tool for the preparation of vapor-phase deposition precursors
Literature Information
Michael A. Land, Katherine N. Robertson, Jason A. C. Clyburne, Seán T. Barry
The volatile bis(tert-butylimido)dichloromolybdenum(VI) compounds, (tBuN)2MoCl2·dad (dad = 1,4-di-tert-butyl-1,3-diazabutadiene) (1) and [(tBuN)2MoCl(μ-Cl)·(tBuNH2)]2 (2), form a eutectic, with a two to one composition (χ2 = 0.33). A decrease of 40 °C in the melting temperature has been observed between the eutectic mixture and the pure compounds. We have isolated a co-crystal of (tBuN)2MoCl2·dme (dme = 1,2-dimethoxyethane) (3) and 2, also in a two to one ratio, which serves as a structural model for such mixtures. The lower melting point of carefully chosen eutectic mixtures can offer more consistent precursor delivery in deposition processes.
Related Literature
Strain tuning of the charge density wave in monolayer and bilayer 1T-TaS2
Li-Yong Gan, Li-Hong Zhang, Qingyun Zhang, Chun-Sheng Guo, Udo Schwingenschlögl
DOI: 10.1039/C5CP05695K
Relationship between vesicle size and steric hindrance influences vesicle rupture on solid supports
DOI: 10.1039/C5CP06786C
Experimental evidence for the influence of charge on the adsorption capacity of carbon dioxide on charged fullerenes
Stefan Ralser, Alexander Kaiser, Michael Probst, Johannes Postler, Michael Renzler, Diethard K. Bohme, Paul Scheier
DOI: 10.1039/C5CP06587A
Ultrafast excited state hydrogen atom transfer in salicylideneaniline driven by changes in aromaticity
Luis Gutiérrez-Arzaluz, Fernando Cortés-Guzmán, Tomás Rocha-Rinza, Jorge Peón
DOI: 10.1039/C5CP03699B
The effect of Mg2+ incorporation on the structure of calcium carbonate clusters: investigation by the anharmonic downward distortion following method
Satoshi Maeda, Takaya Nagai
DOI: 10.1039/C5CP05139H
Zigzag-edge related ferromagnetism in MoSe2 nanoflakes
Baorui Xia, Daqiang Gao, Peitao Liu, Yonggang Liu, Shoupeng Shi, Kun Tao
DOI: 10.1039/C5CP05640C
Micromechanical measurements of the effect of surfactants on cyclopentane hydrate shell properties
Erika P. Brown, Carolyn A. Koh
DOI: 10.1039/C5CP06071K
How can carbon favor planar multi-coordination in boron-based clusters? Global structures of CBxEy2− (E = Al, Ga, x + y = 4)
Zhong-hua Cui, Jing-jing Sui, Yi-hong Ding
DOI: 10.1039/C5CP04776E
Excited-state dynamics of guanosine in aqueous solution revealed by time-resolved photoelectron spectroscopy: experiment and theory
Franziska Buchner, Berit Heggen, Hans-Hermann Ritze, Walter Thiel, Andrea Lübcke
DOI: 10.1039/C5CP04394H
Variable electronic properties of lateral phosphorene–graphene heterostructures
Xiaoqing Tian, Lin Liu, Yu Du, Juan Gu, Jian-bin Xu, Boris I. Yakobson
DOI: 10.1039/C5CP05443E
You might also like
How should waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane be handled?
Waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane (...
How is 7-Fluoro-4-isoquinolinecarboxylic acid (CAS: 1841081-40-0) typically synthesized?
7-Fluoro-4-isoquinolinecarboxylic acid can be synthesized via a multi-step proce...
What are the physical and chemical properties of 2,3,5,6-Tetrabromothieno[3,2-b]thiophene (CAS: 124638-53-5)?
2,3,5,6-Tetrabromothieno[3,2-b]thiophene is a crystalline compound with a high m...
Is 1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indole-4-carboxamide (CAS: 1542705-92-9) safe?
1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indol...
What is the market or research trend for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3-methyl-4-oxo- (CAS: 113942-30-6)?
The market for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3...
What is 3-(Triisopropylsilyl)propiolaldehyde (CAS: 163271-80-5)?
3-(Triisopropylsilyl)propiolaldehyde is a synthetic organic compound with the CA...
What regulatory guidelines apply to 6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1)?
6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1) is subject to various regu...
How should waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piperazinyl)acetic acid (CAS: 885272-91-3) be handled?
Waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piper...
What are the physical and chemical properties of N,N'-4,4'-Biphenyldiyldiisonicotinamide (CAS: 55119-40-9)?
N,N'-4,4'-Biphenyldiyldiisonicotinamide is a white crystalline solid with a mole...
What industries use 6-Bromo-8-fluoro-2-quinazolinol (CAS: 1036756-15-6)?
6-Bromo-8-fluoro-2-quinazolinol is primarily used in the pharmaceutical industry...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














