NMR relaxation time measurements of solvent effects in an organocatalysed asymmetric aldol reaction over silica SBA-15 supported proline
Literature Information
Luke Forster, Simeng Wang, Armando Carlone, Carmine D'Agostino
Immobilisation of organocatalysts onto solid supports represents a very promising solution to tackle their low productivity by enabling their reuse. Herein, the use of NMR relaxation measurements, coupled with reaction screening, was used to investigate the effect of solvent interactions with the immobilised catalyst matrix on reactivity in an asymmetric organocatalysed aldol reaction. Important insights for the further development of such complex, yet promising catalytic systems are provided.
Related Literature
Encapsulation of spherical nanoparticles by colloidal dimers
Gianmarco Munaò, Dino Costa, Carlo Caccamo
DOI: 10.1039/C6CP04704A
Diffusion and precipitation processes in iron-based silica gardens
F. Glaab, J. Rieder, J. M. García-Ruiz, W. Kunz, M. Kellermeier
DOI: 10.1039/C6CP02107G
Deciphering the cryptic role of a catalytic electron in a photochemical bond dissociation using excited state aromaticity markers
Ambar Banerjee, Debabrata Halder, Gaurab Ganguly, Ankan Paul
DOI: 10.1039/C6CP03789E
Tuning thermal transport in Si nanowires by isotope engineering
Miquel Royo, Riccardo Rurali
DOI: 10.1039/C6CP04581B
Shuttle inhibition by chemical adsorption of lithium polysulfides in B and N co-doped graphene for Li–S batteries
Fen Li, Yan Su
DOI: 10.1039/C6CP04071C
Probing ligand-induced modulation of metallic states in small gold nanoparticles using conduction electron spin resonance
Anthony Cirri, Alexey Silakov, Lasse Jensen, Benjamin J. Lear
DOI: 10.1039/C6CP02205G
HONH3Cl optimized CH3NH3PbI3 films for improving performance of planar heterojunction perovskite solar cells via a one-step route
Teng-ling Ye, Bo-yu Pang, Yu-lin Yang, Li Sheng, Yan Shi, Rui-qing Fan, Li-guo Wei, Ting Su
DOI: 10.1039/C6CP05006A
Thermal decomposition of sodium amide, NaNH2, and sodium amide hydroxide composites, NaNH2–NaOH
Peikun Wang, Guotao Wu, Zhitao Xiong, Flemming Besenbacher, Ping Chen, Torben R. Jensen
DOI: 10.1039/C6CP01604A
Towards understanding the kinetic behaviour and limitations in photo-induced copper(i) catalyzed azide–alkyne cycloaddition (CuAAC) reactions
Bassil M. El-Zaatari, Abhishek U. Shete, Brian J. Adzima
DOI: 10.1039/C6CP04950H
Fluorinated photopolymer waveguide thermo-optic switches with loss-compensation function based on erbium-containing cladding structure
Yang Zheng, Changming Chen, Jihou Wang, Zuosen Shi, Zhenzhen Cai, Xiaoqiang Sun, Fei Wang, Zhanchen Cui, Daming Zhang
DOI: 10.1039/C6CP03550G
You might also like
What precautions should be taken when handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2)?
When handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2), it is importan...
Is 4-(4H-1,2,4-Triazol-4-yl)piperidine (CAS: 690261-92-8) safe?
4-(4H-1,2,4-Triazol-4-yl)piperidine is generally considered safe for use in phar...
How should waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) be handled?
Waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) should be collecte...
What regulatory guidelines apply to 5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3)?
5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3) is subject to regulat...
How is Methyl 3-acetamido-2-thiophenecarboxylate (CAS: 22288-79-5) typically synthesized?
Methyl 3-acetamido-2-thiophenecarboxylate can be synthesized by the reaction of ...
What is 4-Isoquinolinecarbonitrile (CAS: 34846-65-6)?
4-Isoquinolinecarbonitrile is a chemical compound with the CAS number 34846-65-6...
How should Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) be stored?
Store Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) in a cool, dry p...
What regulatory guidelines apply to 6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8)?
6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8) is subject to the...
Is (2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) safe?
(2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) ...
What are the physical and chemical properties of 7-bromo-3-methyl-3,4-dihydroquinazolin-4-one (CAS: 1293987-84-4)?
7-Bromo-3-methyl-3,4-dihydroquinazolin-4-one is a solid with a crystalline form....
Source Journal
Reaction Chemistry & Engineering

Reaction Chemistry & Engineering is an interdisciplinary journal reporting cutting-edge research focused on enhancing the understanding and efficiency of reactions. Reaction engineering leverages the interface where fundamental molecular chemistry meets chemical engineering and technology. Challenges in chemistry can be overcome by the application of new technologies, while engineers may find improved solutions for process development from the latest developments in reaction chemistry. Reaction Chemistry & Engineering is a unique forum for researchers whose interests span the broad areas of chemical engineering and chemical sciences to come together in solving problems of importance to wider society. All papers should be written to be approachable by readers across the engineering and chemical sciences. Papers that consider multiple scales, from the laboratory up to and including plant scale, are particularly encouraged.












![(R)-N-[(S)-1-[2-(Diphenylphosphino)phenyl]ethyl]-2-methylpropane-2-sulfinamide structure (R)-N-[(S)-1-[2-(Diphenylphosphino)phenyl]ethyl]-2-methylpropane-2-sulfinamide structure](https://static.chemtradehub.com/structs/159/1595319-98-4-33e7.webp)

