Ionic liquid-derived polyelectrolyte promoting the biphasic condensation of immiscible reactants at moderate temperature

Literature Information

Publication Date 2021-08-27
DOI 10.1039/D1RE00304F
Impact Factor 4.239
Authors

Yuki Kohno, Takashi Makino


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Abstract

A tri-n-octyl(sulfobutyl)phosphonium-based ionic liquid catalyst (ILC1) formed a triphasic system with glycerol and oleic acid, dissolving both reactants and effectively catalysing their condensation to produce glyceryl oleate. An ILC monomer structurally analogous to ILC1 was co-polymerised with divinylbenzene to afford a cross-linked polyelectrolyte promoting the above reaction at <100 °C.

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Source Journal

Reaction Chemistry & Engineering

Reaction Chemistry & Engineering
CiteScore: 0
Self-citation Rate: 8.8%
Articles per Year: 284

Reaction Chemistry & Engineering is an interdisciplinary journal reporting cutting-edge research focused on enhancing the understanding and efficiency of reactions. Reaction engineering leverages the interface where fundamental molecular chemistry meets chemical engineering and technology. Challenges in chemistry can be overcome by the application of new technologies, while engineers may find improved solutions for process development from the latest developments in reaction chemistry. Reaction Chemistry & Engineering is a unique forum for researchers whose interests span the broad areas of chemical engineering and chemical sciences to come together in solving problems of importance to wider society. All papers should be written to be approachable by readers across the engineering and chemical sciences. Papers that consider multiple scales, from the laboratory up to and including plant scale, are particularly encouraged.

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