“In-water” direct arylation polymerization (DArP) under aerobic emulsion conditions

Literature Information

Publication Date 2021-11-09
DOI 10.1039/D1PY01321A
Impact Factor 5.582
Authors

Liwei Ye, Tanin Hooshmand, Barry C. Thompson


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Abstract

Despite limited reports employing sustainable solvents for Direct Arylation Polymerization (DArP), the large amount of organic waste generated from conjugated polymer synthesis requires attention. Herein, we report the first emulsion-DArP methodology to afford polymers with molecular weights up to 14.5 kg mol−1 with a 10-fold reduction of organic solvent utilized.

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Polymer Chemistry

Polymer Chemistry
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