![(R)-N-[(S)-1-[2-(Diphenylphosphino)phenyl]ethyl]-2-methylpropane-2-sulfinamide structure](https://static.chemtradehub.com/structs/159/1595319-98-4-33e7.webp "(R)-N-[(S)-1-[2-(Diphenylphosphino)phenyl]ethyl]-2-methylpropane-2-sulfinamide structure")
(R)-N-[(S)-1-[2-(Diphenylphosphino)phenyl]ethyl]-2-methylpropane-2-sulfinamide
CAS Number:
1595319-98-4
Molecular Formula:
C24H28NOPS
Conjugated microporous polymers using a copper-catalyzed [4 + 2] cyclobenzannulation reaction: promising materials for iodine and dye adsorption
Literature Information
Publication Date
2021-03-17
DOI
10.1039/D1PY00193K
Impact Factor
5.582
Authors
Saleh Al-Mousawi
View Original
Abstract
A design strategy is disclosed to synthesize conjugated microporous polymers (CMPs) using a versatile copper-catalyzed [4 + 2] cyclobenzannulation reaction, which employs a diphenylethynyl terephthalaldehyde derivative 3 with a series of triptycene-based diethynyl aryl building blocks 2a–e. Investigation of the intrinsic microporosity properties of CBP1–5 using nitrogen adsorption measurements reveals Brunauer–Emmett–Teller (BET) surface areas up to 794 m2 g−1 and average pore volumes reaching 0.63 cm3 g−1. Inspection of the adsorption properties of the graphitic-like polymers CBP1–5 divulges their high iodine uptake with a maximum of 166 wt%. Moreover, the target polymers CBP1–5 prove their efficiency as selective dye adsorbents by removing up to 100% methylene blue over methyl orange from aqueous solution.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
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CAS Number:
1020719-57-6
Molecular Formula:
C22H18D5ClN2O2
Ethyl 2,4-bis(trifluoromethyl)-5-pyrimidinecarboxylate
CAS Number:
188781-15-9
Molecular Formula:
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1165450-63-4
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