![(2R,6S)-6-[(Benzyloxy)methyl]-4-{[(2-methyl-2-propanyl)oxy]carbonyl}-2-morpholinecarboxylic acid structure](https://static.chemtradehub.com/structs/109/1093085-91-6-3382.webp "(2R,6S)-6-[(Benzyloxy)methyl]-4-{[(2-methyl-2-propanyl)oxy]carbonyl}-2-morpholinecarboxylic acid structure")
(2R,6S)-6-[(Benzyloxy)methyl]-4-{[(2-methyl-2-propanyl)oxy]carbonyl}-2-morpholinecarboxylic acid
CAS Number:
1093085-91-6
Molecular Formula:
C18H25NO6
Highly efficient UV-Vis light activated three-component photoinitiators composed of tris(trimethylsilyl)silane for polymerization of acrylates
Literature Information
Publication Date
2020-07-23
DOI
10.1039/D0PY00763C
Impact Factor
5.582
Authors
Alicja Balcerak, Dominika Kwiatkowska, Katarzyna Iwińska, Janina Kabatc
View Original
Abstract
The goal of this paper concerns the evaluation of the efficiency of novel three-component systems for initiating the photopolymerization process of 2-ethyl-2-(hydroxymethyl)-1,3-propanediol triacrylate (TMPTA). Combinations of 1,3-bis(phenylamino)squaraine (SQG1) with different types of co-initiators are proposed as effective UV-Vis light photoinitiators. The co-initiators used in the experiments, such as silane (TTMSS), borate salt (B2), carbazole (NVC) and a set of iodonium salts (I1, I2, I77, I81), are active radical sources for initiation of the polymerization of TMPTA. The effect of the composition of the system on the photopolymerization kinetics was analyzed. The optimal photoinitiator concentration that gives high monomer conversions and high values of the rate of polymerization is indicated and presented in this article.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
2-(4,4-Difluorobutyl)-1H-isoindole-1,3(2H)-dione
CAS Number:
1265341-14-7
Molecular Formula:
C12H11F2NO2
Benzyl 6-oxo-3,6-dihydro-1(2H)-pyridinecarboxylate
CAS Number:
725746-35-0
Molecular Formula:
C13H13NO3
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