Facile preparation of polycarbonates from bio-based eugenol and 2-methoxy-4-vinylphenol

Literature Information

Publication Date 2020-06-30
DOI 10.1039/D0PY00291G
Impact Factor 5.582
Authors

Mengqian Huang, De Bai, Qin Chen, Changbo Zhao, Tianhua Ren, Caijuan Huang, Michael North, Haibo Xie


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Abstract

Two α,ω-diene monomers containing a carbonate structure derived from eugenol and 2-methoxy-4-vinylphenol were successfully synthesized in high yields of 94% and 78%, respectively. With these dienes in hand, a series of poly(thioether carbonates) and unsaturated aromatic–aliphatic polycarbonates with moderate molecular weights (Mn) ranging from 17 100 to 24 400 g mol−1 and tunable thermo-properties were prepared via a thiol–ene click reaction and step growth acyclic-diene-metathesis, respectively.

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Polymer Chemistry

Polymer Chemistry
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