Structure-directed formation of the dative/covalent bonds in complexes with C70⋯piperidine
Literature Information
Weizhou Wang, Martin Dračínský
The combined experimental-computational study has been performed to investigate the complexes formed between C70 carbon allotrope and piperidine. The results of FT-IR, H-NMR, and C-NMR measurements, together with the calculations based on the DFT approach and molecular dynamics simulations, prove the existence of dative/covalent bonding in C70⋯piperidine complexes. The dative bond forms not only at the region of five- and six-membered rings, observed previously with C60, but also at the region formed of six-membered rings. The structure, i.e., nonplanarity, explains the observed dative bond formation. New findings on the character of interaction of secondary amines with C70 bring new aspects for the rational design of modified fullerenes and their applications in electrocatalysis, spintronics, and energy storage.
Related Literature
CoCrMo metal-on-metal hip replacements
Yifeng Liao, Emily Hoffman, Markus Wimmer, Alfons Fischer, Joshua Jacobs, Laurence Marks
DOI: 10.1039/C2CP42968C
Enhancing catalytic selectivity of supported metal nanoparticles with capping ligands
Kai Chen, Haotian Wu, Qing Hua, Sujie Chang, Weixin Huang
DOI: 10.1039/C2CP44571A
Prospects for hydrogen storage in graphene
Valentina Tozzini, Vittorio Pellegrini
DOI: 10.1039/C2CP42538F
CO2 capture in poly(ionic liquid) membranes: atomistic insight into the role of anions
Weijie Fang, Zhonglin Luo, Jianwen Jiang
DOI: 10.1039/C2CP42837G
Experimental determination of chemical diffusion within secondary organic aerosol particles
Evan Abramson, Dan Imre, Josef Beránek, Jacqueline Wilson, Alla Zelenyuk
DOI: 10.1039/C2CP44013J
Electrochemistry of nickel nanoparticles is controlled by surface oxide layers
Yi-Ge Zhou, Neil V. Rees, Richard G. Compton
DOI: 10.1039/C2CP43618C
The use of XAFS to determine the nature of interaction of iron and molybdenum metal salts within PS-b-P2VP micelles
Alexander Riskin, Andrew M. Beale, Hans-Gerhard Boyen, André Vantomme, An Hardy
DOI: 10.1039/C2CP43046K
Quantification of silanol sites for the most common mesoporous ordered silicas and organosilicas: total versus accessible silanols
Matthias Ide, Mohamad El-Roz, Els De Canck, Aurélie Vicente, Tom Planckaert, Isabel Van Driessche, Frédéric Lynen, Veronique Van Speybroeck, Frédéric Thybault-Starzyk, Pascal Van Der Voort
DOI: 10.1039/C2CP42811C
Assessment of atomic partial charge schemes for polarisation and charge transfer effects in ionic liquids
Jason Rigby, Ekaterina I. Izgorodina
DOI: 10.1039/C2CP42934A
You might also like
Is 6-(3-Fluorophenyl)picolinic acid (CAS: 887982-40-3) safe?
6-(3-Fluorophenyl)picolinic acid is generally considered safe for laboratory use...
What industries use (3R)-3-Pyrrolidinol (CAS: 2799-21-5)?
(3R)-3-Pyrrolidinol is used in the pharmaceutical industry as a precursor for dr...
What precautions should be taken when handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-8)?
When handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-...
How is 1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone (CAS: 90734-71-7) typically synthesized?
1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone is often synthesized via a mult...
What is the market or research trend for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1)?
The market for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1) remains steady,...
What is Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate (CAS: 1019008-21-9)?
Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate is a chemical compound wit...
What regulatory guidelines apply to 1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1)?
1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1) falls under the classi...
Is 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07-4) safe?
The safety of 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07...
Is Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate (CAS: 22785-43-9) safe?
Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate is generally safe when handled wi...
How should 1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine (CAS: 928657-21-0) be stored?
1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine s...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














