Reversible reduction drives anion ejection and C60 binding within an Fe II4L6 cage
Literature Information
Publication Date
2019-12-05
DOI
10.1039/C9SC05728E
Impact Factor
9.825
Authors
Zhenpin Lu, Tanya K. Ronson, Jonathan R. Nitschke
View Original
Abstract
FeII4L6 tetrahedral cage 1 was prepared from a redox-active dicationic naphthalenediimide (NDI) ligand. The +20 charge of the cage makes it a good host for anionic guests, with no binding observed for neutral aromatic molecules. Following reduction by Cp2Co, the cage released anionic guests; subsequent oxidation by AgNTf2 led to re-uptake of anions. In its reduced form, however, 1 was observed to bind neutral C60. The fullerene guest was subsequently ejected following cage re-oxidation. The guest release process was found to be facilitated by anion-mediated transport from organic to aqueous solution. Cage 1 thus employs electron transfer as a stimulus to control the uptake and release of both neutral and charged guests, through distinct pathways.
Related Literature
Asymmetric tin–vanadium redox electrolyte for hybrid energy storage with nanoporous carbon electrodes
Simon Fleischmann
2017-01-05
Paper
DOI: 10.1039/C6SE00062B
Imaging phosphorylated peptide distribution in human lens by MALDI MS
Aizhu Miao, Qi Fan, Yi Lu
2015-04-20
Paper
DOI: 10.1039/C5AN00101C
Nitrogen and iron codoped porous carbon polyhedra for effectively confining polysulfides and efficiently catalyzing their conversion in lithium–sulfur batteries
Shahzad Ahmad Khan, Dengke Zhao, Zexing Wu, Shaowei Chen
2020-08-07
Paper
DOI: 10.1039/D0SE00942C
Hybrid energy storage of battery-type nickel hydroxide and supercapacitor-type graphene: redox additive and charge storage mechanism
Atiweena Krittayavathananon, Peerapan Dittanet, Pinit Kidkhunthod, Montree Sawangphruk
2017-02-23
Paper
DOI: 10.1039/C7SE00052A
The improvement of photocatalytic performance for hydrogen evolution over mesoporous g-C3N4 modified with nitrogen defects
Lei Liang, Lei Shi, Fangxiao Wang, Haihua Wang, Wei Qi
2020-07-29
Paper
DOI: 10.1039/D0SE01012J
Efficient production of lactic acid from biomass-derived carbohydrates under synergistic effects of indium and tin in In–Sn-Beta zeolites
Meng Xia, Wenjie Dong, Shaoze Xiao, Wenbo Chen, Minyan Gu, Yalei Zhang
2020-09-08
Paper
DOI: 10.1039/D0SE00798F
Sustainable production of nano α-Fe2O3/N-doped biochar hybrid nanosheets for supercapacitors
Panyu Li, Hongyang Xie, Xuqian Wang, Yi Xie, Yabo Wang, Yongkui Zhang
2020-06-15
Paper
DOI: 10.1039/D0SE00627K
Cu3P/PAN derived N-doped carbon catalyst with non-toxic synthesis for alkaline hydrogen evolution reaction
HyoWon Kim, Yongju Lee, DongHoon Song, YongKeun Kwon, Eom-Ji Kim, EunAe Cho
2020-08-26
Paper
DOI: 10.1039/D0SE00923G
Boric acid: the first effective inorganic promoter for methane hydrate formation under static conditions
Yanxian Zeng, Xiaochun Niu, Dongjun Lei, Zhengwen Liu, Zhengmei Zhu, Weixing Wang
2020-07-10
Communication
DOI: 10.1039/D0SE00640H
You might also like
Compound Q&A
Is 2-(2-chloroacetamido)-3-phenylpropanoic acid (CAS: 7765-11-9) safe?
2-(2-Chloroacetamido)-3-phenylpropanoic acid (CAS: 7765-11-9) is generally consi...
7765-11-92-(2-chloroacetamido...
Compound Q&A
Is 2-(Benzyloxy)-5-bromobenzoic acid (CAS: 62176-31-2) safe?
2-(Benzyloxy)-5-bromobenzoic acid can be handled safely if appropriate precautio...
62176-31-22-(Benzyloxy)-5-brom...
Compound Q&A
What is (4-Methyl-1,2,5-oxadiazol-3-yl)methanamine hydrochloride (CAS: 1159825-48-5)?
(4-Methyl-1,2,5-oxadiazol-3-yl)methanamine hydrochloride is a chemical compound ...
1159825-48-5(4-Methyl-1,2,5-oxad...
Compound Q&A
What is 2-(5-Hexylthiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (CAS: 917985-54-7)?
2-(5-Hexylthiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (CAS: 917985-54...
917985-54-72-(5-Hexylthiophen-2...
Compound Q&A
Are there alternatives to 4-(8-Methyl-9H-1,3-dioxolo[4,5-h][2,3]benzodiazepin-5-yl)benzenamine (CAS: 102771-26-6) in synthesis?
While 4-(8-Methyl-9H-1,3-dioxolo[4,5-h][2,3]benzodiazepin-5-yl)benzenamine (CAS:...
102771-26-64-(8-Methyl-9H-1,3-d...
Compound Q&A
What is the market or research trend for tert-butyl 3-hydroxy-4,5,7,8-tetrahydro-2H-pyrazolo[3,4-d]azepine-6-carboxylate (CAS: 851376-80-2)?
The market for tert-butyl 3-hydroxy-4,5,7,8-tetrahydro-2H-pyrazolo[3,4-d]azepine...
851376-80-2tert-butyl 3-hydroxy...
Compound Q&A
How should waste containing 3,5-Diamino-1H-pyrazole-4-carbonitrile (CAS: 6844-58-2) be handled?
Waste containing 3,5-Diamino-1H-pyrazole-4-carbonitrile (CAS: 6844-58-2) should ...
6844-58-23,5-Diamino-1H-pyraz...
Compound Q&A
How is (6-Fluoro-3-pyridinyl)boronic acid (CAS: 351019-18-6) typically synthesized?
(6-Fluoro-3-pyridinyl)boronic acid can be synthesized through the reaction of 6-...
351019-18-6(6-Fluoro-3-pyridiny...
Compound Q&A
What industries use Dibenzyl carbonimidoylbiscarbamate (CAS: 10065-79-9)?
Dibenzyl carbonimidoylbiscarbamate (CAS: 10065-79-9) finds applications in vario...
10065-79-9Dibenzyl carbonimido...
Compound Q&A
What is the market or research trend for (beta,beta,2,3,4,5,6-~2~H_7_)Phenylalanine (CAS: 74228-83-4)?
The market for (beta,beta,2,3,4,5,6-~2~H_7_)Phenylalanine (CAS: 74228-83-4) is g...
74228-83-4(beta,beta,2,3,4,5,6...
Source Journal
Chemical Science
CiteScore:
14.4
Self-citation Rate:
3.9%
Articles per Year:
1413
Our journal has a wide-ranging scope which covers the full breadth of the chemical sciences. The research we publish contains the sorts of novel ideas, challenging questions and progressive thinking that bring undiscovered breakthroughs within reach. Your paper could focus on a single area, or cross many. It could be beyond the accepted bounds of the chemical sciences. It might address an immediate challenge, contribute to a future breakthrough or be wholly conceptual. We’re a team from every field of the chemical sciences, and know from experience that breakthroughs that drive the solutions to global challenges can come from anywhere, at any time. You could even start an entirely new area of research. Too bold? Too progressive? No such thing
Recommended Compounds
4-(3-((4-Chloro-6-methoxyquinolin-7-yl)oxy)propyl)morpholine
CAS Number:
205448-32-4
Molecular Formula:
C17H21ClN2O3
![2-Azaspiro[4.5]decane-3,8-dione structure](https://static.chemtradehub.com/structs/914/914780-96-4-e94b.webp "2-Azaspiro[4.5]decane-3,8-dione structure")
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.