Visible-light-promoted hydroxysulfonylation of alkylidenecyclopropanes: synthesis of cyclopropane-containing β-hydroxysulfones
Literature Information
Publication Date
2019-10-25
DOI
10.1039/C9QO01058K
Impact Factor
5.281
Authors
Chuang Liu, Yan-Jie Yang, Jun-Ying Dong, Ming-Dong Zhou, Lei Li, He Wang
View Original
Abstract
Visible-light-promoted hydroxysulfonylation of the C–C double bond of alkylidenecyclopropanes (ACPs) with conservation of the cyclopropyl ring has been developed. The difunctionalization reaction exhibits a broad substrate scope with excellent functional group compatibility, affording a series of cyclopropane-containing β-hydroxysulfones and cyclopropyl styrenes in 34–91% yields under mild conditions. The preliminary mechanistic investigation indicates that this difunctionalization reaction includes a radical process via a sulfone radical.
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Source Journal
Organic Chemistry Frontiers
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