A radical-chain reaction of isocyanides with selenosulfonates and water: facile synthesis of selenocarbamates under metal-free conditions
Literature Information
Publication Date
2019-01-22
DOI
10.1039/C8QO01364K
Impact Factor
5.281
Authors
Yi Fang, Can Liu, Fei Wang, Rao Ding, Shun-Yi Wang, Shun-Jun Ji
View Original
Abstract
A facile synthesis of secondary selenocarbamates through metal-free multicomponent reactions of isocyanides, selenosulfonates and water is reported here. The reaction is easy to handle and proceeds smoothly under mild conditions. The desired products are isolated in good yields with broad tolerance of functional groups. Detailed investigation of the mechanism is conducted and a radical-chain reaction model is also proposed.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
2-Methyl-2-propanyl 4-iodo-1-piperidinecarboxylate
CAS Number:
301673-14-3
Molecular Formula:
C10H18INO2
![2,9-Dichloro-5,12-dihydroquinolino[2,3-b]acridine-7,14-dione structure](https://static.chemtradehub.com/structs/308/3089-17-6-750b.webp "2,9-Dichloro-5,12-dihydroquinolino[2,3-b]acridine-7,14-dione structure")
2,9-Dichloro-5,12-dihydroquinolino[2,3-b]acridine-7,14-dione
CAS Number:
3089-17-6
Molecular Formula:
C20H10Cl2N2O2
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