![trans-2-{[(Tert-butoxy)carbonyl]amino}cyclobutane-1-carboxylic acid structure](https://static.chemtradehub.com/structs/951/951173-25-4-27cd.webp "trans-2-{[(Tert-butoxy)carbonyl]amino}cyclobutane-1-carboxylic acid structure")
trans-2-{[(Tert-butoxy)carbonyl]amino}cyclobutane-1-carboxylic acid
CAS Number:
951173-25-4
Molecular Formula:
C10H17NO4
Synthesis of 1-naphthols via Cp*Co(iii)-catalyzed C–H activation and cyclization of sulfoxonium ylides with alkynes
Literature Information
Publication Date
2019-10-12
DOI
10.1039/C9QO00994A
Impact Factor
5.281
Authors
Yongqi Yu, Qianlong Wu, Da Liu, Lin Yu, Ze Tan, Gangguo Zhu
View Original
Abstract
A highly practical and efficient synthesis of 1-naphthols was developed via Cp*Co(III)-catalyzed C–H activation and cascade [4 + 2] cyclization between sulfoxonium ylides and alkynes, during which the sulfoxonium ylide functioned as a traceless directing group. This method features operational simplicity, redox-neutral reaction conditions, excellent regioselectivity and good substrate compatibility, and various 1-naphthols were efficiently synthesized in 36–92% yields.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
2,3,6-Tri-O-acetyl-4-O-(2,3,4,6-tetra-O-acetyl-beta-D-galactopyranosyl)-alpha-D-glucopyranosyl bromide
CAS Number:
4753-07-5
Molecular Formula:
C26H35BrO17
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