Aztreonam USP Related Compound A (Open-ring Aztreonam)
CAS Number:
87500-74-1
Molecular Formula:
C13H19N5O9S2
Visible-light-induced radical hydrodifluoromethylation of alkenes
Literature Information
Publication Date
2019-09-05
DOI
10.1039/C9QO00919A
Impact Factor
5.281
Authors
Jiao Yu, Jin-Hong Lin, Yu-Cai Cao, Ji-Chang Xiao
View Original
Abstract
Described here is the radical-mediated hydrodifluoromethylation of alkenes that occurs under transition-metal-free conditions by using the phosphonium salt [Ph3P+CF2H]Br− under the irradiation of 26 W household compact fluorescent light. The reaction lends itself to a convenient protocol for the installation of a C–CF2H bond while maintaining good functional group tolerance.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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CAS Number:
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Molecular Formula:
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CAS Number:
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Molecular Formula:
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