4,4,5,5-Tetramethyl-2-(1-propyn-1-YL)-1,3,2-dioxaborolane
CAS Number:
347389-75-7
Molecular Formula:
C9H15BO2
Carbonylative transformation of benzyl formates into alkyl 2-arylacetates in organic carbonates
Literature Information
Publication Date
2019-08-15
DOI
10.1039/C9QO00917E
Impact Factor
5.281
Authors
Xinxin Qi, Ming Lai
View Original
Abstract
A carbonylation procedure for the transformation of benzyl formates in organic carbonates has been developed. In this reaction, benzyl formates were successfully applied as both the CO source and benzyl alcohol substrates. Additionally, organic carbonates played multiple roles as a green solvent, an in situ activator, and a nucleophile in this procedure; various alkyl 2-arylacetates could be obtained in moderate to excellent yields.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
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