Rh(i)-Catalyzed intramolecular [3 + 2] cycloaddition reactions of yne-vinylidenecyclopropanes
Literature Information
Publication Date
2019-04-03
DOI
10.1039/C9QO00343F
Impact Factor
5.281
Authors
Kang-Hua Rui
View Original
Abstract
A cationic Rh(I) complex-catalyzed intramolecular [3 + 2] cycloaddition reaction of newly developed yne-vinylidenecyclopropanes (VDCPs) has been established, affording an efficient synthesis of fused [6.5]-bicyclic structures in moderate to good yields under mild conditions. Moreover, the reaction exhibits a broad substrate scope along with good functional group tolerance.
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Organic Chemistry Frontiers
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