Femtosecond investigations on the ultrafast photo-dissociation dynamics of CpMn(CO)3 and its fragment ions
Literature Information
Cosmin Lupulescu, Štefan Vajda, Albrecht Lindinger, Andrea Merli, Ludger Wöste
This work is devoted to investigation on the ultrafast dissociation phenomena of the cyclopentadienyl manganese tricarbonyl–CpMn(CO)3− molecule and its emerging fragments by means of mass spectrometry and pump–probe spectroscopy. Studies on the laser intensity and wavelength dependence observed in the recorded mass spectra are reported. Time-resolved mass spectra were measured in order to investigate the fragmentation time scale. From the recorded two-color pump and probe spectra the lifetimes of the electronically excited states for all CpMn(CO)n+ (1 ≤ n ≤ 3) ions were extracted. By employing laser pulses of ca. 40 fs, wave packet dynamics of the parent ion CpMn(CO)3+ as well as for the first fragment have been resolved. These findings have already been successfully exploited in optimal control experiments. The present studies are extended to different pump pulse intensities.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














