Copper-catalyzed direct C–H phosphorylation of N-imino isoquinolinium ylides with H-phosphonates
Literature Information
Publication Date
2019-03-15
DOI
10.1039/C9QO00107G
Impact Factor
5.281
Authors
Xin-Chen Zhan, Yu-Yuan Hei, Jian-Lan Song, Peng-Cheng Qian, Xing-Guo Zhang, Chen-Liang Deng
View Original
Abstract
A new and efficient protocol for the synthesis of phosphorus-containing isoquinoline skeletons via copper-catalyzed direct C–H phosphorylation of N-iminoisoquinolinium ylides with H-phosphonates has been described. A variety of N-iminoisoquinolinium ylides reacted under the ligand and oxidant free conditions smoothly to afford phosphorylated isoquinolines in moderate to excellent yields.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
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724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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Molecular Formula:
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