In-situ spin trap electron paramagnetic resonance study of fuel cell processes

Literature Information

Publication Date 2004-04-28
DOI 10.1039/B404253K
Impact Factor 3.676
Authors

Alexander Panchenko, Herbert Dilger, Jochen Kerres, Martin Hein, Andreas Ullrich, Till Kaz, Emil Roduner


View Original

Abstract

A novel method allows the monitoring of radical formation and membrane degradation in-situ in a working fuel cell which is placed in the microwave resonator of an electron paramagnetic resonance (EPR) spectrometer. By introduction of a spin trap molecule at the cathode the formation of immobilized organic radicals on the membrane surface is observed for F-free membranes, revealing the onset of oxidative degradation. For NafionĀ® there is much less evidence of degradation, and the hydroxyl radical is detected instead. At the anode, free radical intermediates of the fuel oxidation process are observed. No traces of membrane degradation are detected on this side of the fuel cell.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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