Thiolation of NHC-boranes: influence of the substitution at boron

Literature Information

Publication Date 2019-04-02
DOI 10.1039/C9OB00578A
Impact Factor 3.876
Authors

Anne-Laure Vallet, Emmanuel Lacôte


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Abstract

Several N-Heterocyclic Carbene (NHC)-boryl sulfides with B-substituents were prepared. The added steric hindrance leads to much improved selectivities as only the NHC-boryl mono-sulfides were obtained. The B-substituted NHC-boranes are also conducive to more selective S to N NHC-boryl shift, provided that the NHC used is not too sterically demanding.

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Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry
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