Unusual temperature-sensitive excimer fluorescence from discrete π–π dimer stacking of anthracene in a crystal

Literature Information

Publication Date 2019-06-17
DOI 10.1039/C9CP02656H
Impact Factor 3.676
Authors

Yue Shen, Haichao Liu, Jungang Cao, Shitong Zhang, Weijun Li, Bing Yang


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Abstract

Herein, an unusual blue shift in excimer fluorescence with increasing temperature was observed from a crystal with a discrete π–π anthracene dimer, originating from the more temperature-sensitive intermolecular geometry of the π–π dimer (e.g., π–π distance) compared to the intramolecular geometry of the monomer, which is confirmed by temperature-dependent single-crystal X-ray diffraction (XRD) measurements.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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