Biomimetic synthesis of nudicaulins I and II, yellow pigments from the Iceland poppy Papaver nudicaule

Literature Information

Publication Date 2019-10-21
DOI 10.1039/C9CC07943B
Impact Factor 6.222
Authors

Rory Devlin, Jonathan Sperry


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Abstract

Indole and the anthocyanin orientalin proceed through a unique cascade sequence that leads to nudicaulins I and II in 92% yield. This biomimetic synthesis confirms the biosynthesis proposal for these structurally unprecedented flavoalkaloids that play a key role in the colour range displayed by the Iceland poppy.

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