Facile synthesis of conjugated microporous polymer-based porphyrin units for adsorption of CO2 and organic vapors

Literature Information

Publication Date 2019-01-10
DOI 10.1039/C8PY01476K
Impact Factor 5.582
Authors

Di Cui, Shuran Zhang, Guangjuan Xu, Zhongmin Su


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Abstract

We present two novel porphyrin (Porp)-based conjugated microporous polymers (CMPs; Porp-TPE-CMP and Porp-Py-CMP), formed via an FeCl3-catalyzed cross-coupling reaction between pyrrole and aromatic aldehyde. The resultant CMPs exhibited high CO2 selectivity compared with N2 and CH4, and good capacity for organic vapors.

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Polymer Chemistry

Polymer Chemistry
CiteScore: 8.6
Self-citation Rate: 7.3%
Articles per Year: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

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