Ethyl 2,4-bis(trifluoromethyl)-5-pyrimidinecarboxylate
CAS Number:
188781-15-9
Molecular Formula:
C9H6F6N2O2
Metallocene influence on poly(cyclosilane) structure and properties
Literature Information
Publication Date
2018-03-26
DOI
10.1039/C8PY00312B
Impact Factor
5.582
Authors
Carlton P. Folster, Rebekka S. Klausen
View Original
Abstract
Poly(cyclosilane)s, conjugated polymers inspired by crystalline silicon, are synthesized by group 4 metallocene-promoted dehydrocoupling polymerization. Changes in metallocene structure and reactivity are correlated with changes in poly(cyclosilane) chain length and optical properties. This work demonstrates the ability of target-directed synthesis to afford tunable, complex polymeric architectures.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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CAS Number:
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