Improved transparency–nonlinearity trade-off with boroxine-based octupolar molecules

Literature Information

Publication Date 2003-10-09
DOI 10.1039/B308664J
Impact Factor 6.222
Authors

Gilles Alcaraz, Lisenn Euzenat, Olivier Mongin, Claudine Katan, Isabelle Ledoux, Joseph Zyss, Mireille Blanchard-Desce, Michel Vaultier


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Abstract

A series of octupolar molecules derived from the boroxine framework were designed and their optical nonlinearities were investigated by performing harmonic light scattering experiments in solution; the molecules were found to combine excellent transparency in the near UV-visible region (λmax ≤ 280 nm) and significant first-order hyperpolarisabilities (up to β(0) = 56 × 10−30 esu).

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