Helical templating of polyiodide networks at a binuclear metallo complex

Literature Information

Publication Date 2003-01-14
DOI 10.1039/B211743F
Impact Factor 6.222
Authors

Caitlin J. Horn, Alexander J. Blake, Neil R. Champness, Alessandra Garau, Vito Lippolis, Claire Wilson, Martin Schröder


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Abstract

A homobimetallic supramolecular helicate has been prepared from a new multimodal ligand, and used to template the formation of two polyiodide networks, one containing an unprecedented figure-of-eight polyiodide helix, the other dominated by peripheral C–H⋯I polyiodide chain interactions.

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