Photoinduced Ba2+ release and thermal rebinding by an azacrown ether linked by an alkynyl pyridine to a (bpy)Re(CO)3 group

Literature Information

Publication Date 2003-10-22
DOI 10.1039/B309436G
Impact Factor 6.222
Authors

Jared D. Lewis, John N. Moore


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Abstract

A novel complex in which an azacrown ether is linked by an alkynyl pyridine to a (bpy)Re(CO)3 group acts as a light-controlled ion switch: Ba2+ bound to the azacrown is released in ca. 10 ns on UV excitation, and rebinds thermally from bulk solution in ca. 1 µs.

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