Self-assembly of a unique hexadecanuclear [4 × (2 × 2)]-Pb16  ‘grid of grids’ type structure

Literature Information

Publication Date 2003-10-28
DOI 10.1039/B308512K
Impact Factor 6.222
Authors

Stuart T. Onions, Anthony M. Frankin, Peter N. Horton, Michael B. Hursthouse, Craig J. Matthews


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Abstract

A new ligand containing a linear sequence of four-tridentate chelating subunits built around alkoxide and pyrimidine bridging groups undergoes a spontaneous self-assembly process with Pb(CF3SO3)2 to produce a unique hexadecanuclear [4 × (2 × 2)] ‘grid of grids’ type structure with external dimensions of 26 Å.

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