Rh-Catalyzed aminative dearomatization of 2-naphthols

Literature Information

Publication Date 2018-10-31
DOI 10.1039/C8OB02592D
Impact Factor 3.876
Authors

Hang-Fei Tu


View Original

Abstract

A direct aminative dearomatization of 2-naphthols was achieved. In the presence of 1 mol% Rh2(esp)2 and 3 equivalents of O-(2,4-dinitrophenyl)hydroxylamine (DPH) as readily available aminating reagents, the reactions of 2-naphthols afforded unprotected α-amino-β-naphthalenones in good yields under mild reaction conditions. The conditions were compatible with gram-scale reaction, and the product could undergo diverse transformations.

Related Literature

Highly efficient terpolymerizations of ethylene/propylene/ENB with a half-titanocene catalytic system

Yi-Cong Wang, Pei-Yi Cheng, Zhi-Qian Zhang, Ke-Xin Fan, Rui-Qi Lu, Shu Zhang, Yi-Xian Wu

2021-10-29 Paper

DOI: 10.1039/D1PY01140E

Contents list

Front/Back Matter

DOI: 10.1039/D0PY90148B

Designing self-propagating polymers with ultrasensitivity through feedback signal amplification

Jiajia Tan, Jinming Hu, Shiyong Liu

2021-10-12 Minireview

DOI: 10.1039/D1PY01095F

Identifying competitive tin- or metal-free catalyst combinations to tailor polyurethane prepolymer and network properties

Priscilla Arnould, Lionel Bosco, Federico Sanz, Frédéric N. Simon, Stéphane Fouquay, Guillaume Michaud, Jean Raynaud, Vincent Monteil

2020-08-25 Paper

DOI: 10.1039/D0PY00864H

Development of physical, mechanical, antibacterial and cell growth properties of poly(glycerol sebacate urethane) (PGSU) with helping of curcumin and hydroxyapatite nanoparticles

Vafa Fakhri, Aliakbar Jafari, Mir Alireza Shafiei, Mohammad Vahid Ehteshamfar, Shima Khalighiyan, Hadi Hosseini, Vahabodin Goodarzi, Frederik R. Wurm, Mehrdad Moosazadeh Moghaddam

2021-10-19 Paper

DOI: 10.1039/D1PY01040A

Polymer actuators based on covalent adaptable networks

Yahe Wu, Yan Ji

2020-05-14 Review Article

DOI: 10.1039/D0PY00075B

Reversible cyclic-linear topological transformation using a long-range rotaxane switch

Daisuke Aoki, Gota Aibara

2021-10-07 Communication

DOI: 10.1039/D1PY01197A

Alginate-based diblock polymers: preparation, characterization and Ca-induced self-assembly

Amalie Solberg, Ingrid V. Mo, Finn L. Aachmann, Christophe Schatz, Bjørn E. Christensen

2021-09-09 Paper

DOI: 10.1039/D1PY00727K

You might also like

Compound Q&A

What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?

N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...

52818-63-0N-(4-Methoxybenzyl)-...
Compound Q&A

What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?

When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...

1050507-06-6Ethyl 4-(2-chlorophe...
Compound Q&A

What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?

Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...

628-39-7Diethyldiselane
Compound Q&A

What is the market or research trend for oxocopper (CAS: 12053-18-8)?

The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...

12053-18-8oxocopper; oxo-(oxoc...
Compound Q&A

What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?

The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...

1268519-54-55-{[(2-Methyl-2-prop...
Compound Q&A

What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?

2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...

35981-63-62-(1-Pyrrolidinyl)-4...
Compound Q&A

What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?

2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...

91556-75-12-(3-Pyridinyl)-1-az...
Compound Q&A

How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?

(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...

129704-91-2(S)-Alpha-allyl-prol...
Compound Q&A

What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?

3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...

4857-42-53-Methyl-1,2-oxazole...
Compound Q&A

How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?

Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...

1281816-04-3Lys-SMCC-DM1

Source Journal

Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry
CiteScore: 3.4
Self-citation Rate: 10.3%
Articles per Year: 1041

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.