A cascade synthesis of S-allyl benzoylcarbamothioates via Mumm-type rearrangement
Literature Information
Anjali Dahiya, Wajid Ali, Tipu Alam, Bhisma K. Patel
A catalyst and solvent free synthesis of S-allyl benzoylcarbamothioates has been achieved from the in situ generated benzoylcarbonimidothioates obtained by reacting MBH alcohols with aroyl isothiocyanates. An intramolecular thia-Michael addition of the in situ generated adduct triggers a Mumm-type rearrangement leading to a stereoselective synthesis of highly functionalised S-allyl benzoylcarbamothioates.
Related Literature
Synthesis of metal–organic frameworks by continuous flow
Peter A. Bayliss, Eduardo Pérez, Sihai Yang, Chiu C. Tang, Martyn Poliakoff, Martin Schröder
DOI: 10.1039/C4GC00313F
Expanding the scope of enzymatic carboligation reactions in flow-mode: production of optically active tertiary alcohols with packed-bed micro-bioreactors
P. P. Giovannini, O. Bortolini, A. Cavazzini, R. Greco, G. Fantin, A. Massi
DOI: 10.1039/C4GC00838C
t-BuXPhos: a highly efficient ligand for Buchwald–Hartwig coupling in water
Patrick Wagner, Maud Bollenbach, Christelle Doebelin, Frédéric Bihel, Jean-Jacques Bourguignon, Martine Schmitt
DOI: 10.1039/C4GC00853G
Selective conversion of lignin in corncob residue to monophenols with high yield and selectivity
Zhicheng Jiang, Ting He, Jianmei Li, Changwei Hu
DOI: 10.1039/C4GC00620H
Gold supported on titania for specific monohydrogenation of dinitroaromatics in the liquid phase
Shuang-Shuang Liu, Xiang Liu, Lei Yu, Yong-Mei Liu, He-Yong He, Yong Cao
DOI: 10.1039/C4GC00869C
Sustainable chromatography (an oxymoron?)
Emily A. Peterson, Barry Dillon, Izzat Raheem, Paul Richardson, Daniel Richter, Rachel Schmidt, Helen F. Sneddon
DOI: 10.1039/C4GC00615A
Efficient photocatalytic Suzuki cross-coupling reactions on Au–Pd alloy nanoparticles under visible light irradiation
Qi Xiao, Sarina Sarina, Esa Jaatinen, Jianfeng Jia, Dennis P. Arnold, Hongwei Liu, Huaiyong Zhu
DOI: 10.1039/C4GC00588K
Furfural from corn stover hemicelluloses. A mineral acid-free approach
Hilda Gómez Bernal, Luca Bernazzani
DOI: 10.1039/C4GC00450G
Integrated conversion of agroindustrial residue with high pressure CO2 within the biorefinery concept
Ana R. C. Morais, Ana C. Mata, Rafal Bogel-Lukasik
DOI: 10.1039/C4GC01093K
Additions and corrections published 20th December 2013 to 1st April 2014
DOI: 10.1039/C4GC90034K
You might also like
How should 2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) be stored?
2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) should be stored in ...
Is (1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide (CAS: 132747-20-7) safe?
(1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide is generally considered sa...
What industries use (6-Chloropyridazin-3-YL)methanamine (CAS: 871826-15-2)?
(6-Chloropyridazin-3-YL)methanamine finds applications in the pharmaceutical ind...
What are the main uses of 2-Fluoro-3-methylphenol (CAS: 77772-72-6)?
2-Fluoro-3-methylphenol is primarily used in the synthesis of pharmaceuticals, p...
What precautions should be taken when handling 3-Methoxy-4-nitrobenzonitrile (CAS: 177476-75-4)?
When handling 3-Methoxy-4-nitrobenzonitrile, it is important to wear appropriate...
What precautions should be taken when handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4)?
When handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4), it is ...
What regulatory guidelines apply to 4-Ethynylbenzamide (CAS: 90347-86-7)?
4-Ethynylbenzamide (CAS: 90347-86-7) falls under various regulatory guidelines i...
What are the main uses of 3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone (CAS: 186822-57-1)?
3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone is primarily used as an intermediat...
What is (2-Fluoro-6-methoxyphenyl)acetic acid (CAS: 500912-19-6)?
(2-Fluoro-6-methoxyphenyl)acetic acid, also known as 4-fluoro-3-methoxybenzoic a...
What is the market or research trend for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9)?
Market trends for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9) indicat...
Source Journal
Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.












![5-Bromo-3-isopropyl-1H-pyrrolo[2,3-b]pyridine structure 5-Bromo-3-isopropyl-1H-pyrrolo[2,3-b]pyridine structure](https://static.chemtradehub.com/structs/125/1256819-54-1-8620.webp)
