Silver-catalyzed regioselective hydroamination of alkenyl diazoacetates to synthesize γ-amino acid equivalents
Literature Information
Jun Ueda, Shingo Harada, Hiroki Nakayama
A simple protocol to directly access γ-amino acid derivatives by intermolecular regioselective hydroamination of trichloroethyl alkenyldiazoacetates with carbamate using a silver tetrafluoroborate catalyst is described. Density functional theory (DFT) calculations to analyze the reaction mechanism revealed that multiple attractive interactions occur in a transition state to promote the vinylogous addition of nitrogen nucleophiles.
Recommended Journals

Current Opinion in Colloid & Interface Science

Russian Journal of Applied Chemistry

Saudi Pharmaceutical Journal

Organic Process Research & Development

New Journal of Chemistry

Russian Chemical Bulletin

Russian Journal of Organic Chemistry

Journal of Saudi Chemical Society

Russian Journal of Bioorganic Chemistry

Russian Journal of Coordination Chemistry
Related Literature
On the structure and bonding in the B4O4+ cluster: a boron oxide analogue of the 3,5-dehydrophenyl cation with π and σ double aromaticity
Ting Ou, Wen-Juan Tian, Xue-Rui You, Kang Wang
DOI: 10.1039/C5CP04519C
Geometry controlled anomalous diffusion in random fractal geometries: looking beyond the infinite cluster
DOI: 10.1039/C5CP03548A
Stable n-type doping of graphene via high-molecular-weight ethylene amines
Insu Jo, Joonhee Moon, Subeom Park, Jin San Moon, Won Bae Park, Jeong Soo Lee, Byung Hee Hong
DOI: 10.1039/C5CP03196F
Local electric fields and molecular properties in heterogeneous environments through polarizable embedding
Nanna Holmgaard List, Hans Jørgen Aagaard Jensen, Jacob Kongsted
DOI: 10.1039/C6CP00669H
Theoretical prediction of silicene as a new candidate for the anode of lithium-ion batteries
Seyedeh Mozhgan Seyed-Talebi, Iraj Kazeminezhad, Javad Beheshtian
DOI: 10.1039/C5CP04666A
Electrochemical oxidation of 2-propanol over platinum and palladium electrodes in alkaline media studied by in situ attenuated total reflection infrared spectroscopy
Takeou Okanishi, Yu Katayama, Ryota Ito, Hiroki Muroyama, Toshiaki Matsui, Koichi Eguchi
DOI: 10.1039/C5CP07518A
Theoretical evidence of charge transfer interaction between SO2 and deep eutectic solvents formed by choline chloride and glycerol
Hongping Li, Yonghui Chang, Wenshuai Zhu, Changwei Wang, Chao Wang, Sheng Yin, Ming Zhang
DOI: 10.1039/C5CP04172D
Unique insight into phase separation in polymer solar cells from their electric characteristics
Jian Wang, Fujun Zhang, Qiaoshi An, Qianqian Sun, Jian Zhang
DOI: 10.1039/C5CP05471K
A new insight into the nanostructure of alkylammonium alkanoates based ionic liquids in water
Umme Salma, Paolo Ballirano, Marianna Usula, Ruggero Caminiti, Natalia V. Plechkova, Kenneth R. Seddon, Lorenzo Gontrani
DOI: 10.1039/C5CP07953E
A magnetooptical study of (4-(2-dibutylaminoethanolato-N,O,O,O) chlorido copper(ii)): a cubane complex with dominant ferromagnetic interactions
Serghei M. Ostrovsky, Zbigniew Tomkowicz, Wolfgang Haase
DOI: 10.1039/C5CP05836H
You might also like
What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?
N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...
What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?
When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...
What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?
Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...
What is the market or research trend for oxocopper (CAS: 12053-18-8)?
The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...
What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?
The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...
What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?
2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...
What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?
2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...
How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?
(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...
What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?
3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...
How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?
Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...
Source Journal
Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.

![1,10-bis(3,5-dimethylphenyl)-12-hydroxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine 12-oxide structure 1,10-bis(3,5-dimethylphenyl)-12-hydroxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine 12-oxide structure](https://static.chemtradehub.com/structs/141/1412439-82-7-b9a9.webp)


