Spectroscopic characterisation of centropolyindanes
Literature Information
Stewart F. Parker, Lisha Zhong, Marco Harig, Dietmar Kuck
A highly promising class of three-dimensional polyaromatic hydrocarbons comprises the centropolyindanes. The characteristic feature of these compounds is the mutual fusion of several molecules of indane along the saturated C–C bonds of their cyclopentane rings. Among the polycyclic aromatic hydrocarbons, the centropolyindanes are special because of the saturated core of sp3-hybridised carbon atoms embedded in a three-dimensional environment of aromatic building blocks. While the centropolyindanes and their numerous derivatives have been studied in detail by NMR spectroscopy, mass spectrometry and X-ray diffraction, investigation of their vibrational features, and especially those of the neopentane core present in most cases, have not been performed so far. In the present paper, we report the first systematic study of a set of centropolyindanes by vibrational spectroscopy, using inelastic neutron scattering (INS), infrared and Raman spectroscopies.
Recommended Journals

Journal of Enzyme inhibition and Medicinal Chemistry

Angewandte Chemie International Edition

Environmental Toxicology and Pharmacology

Foundations of Chemistry

Molecules

Faraday Discussions

Contact Lens & Anterior Eye

Photochemical & Photobiological Sciences

European Journal of Organic Chemistry

Physical Chemistry Chemical Physics
Related Literature
An expeditive and green chemo-enzymatic route to diester sinapoyl-l-malate analogues: sustainable bioinspired and biosourced UV filters and molecular heaters
Benjamin Rioux, Louis M. M. Mouterde, Jimmy Alarcan, Matthias J. A. Vink, Jack M. Woolley, Aurélien A. M. Peru, Matthieu M. Mention, Fanny Brunissen, Giel Berden, Jos Oomens, Albert Braeuning, Florent Allais
DOI: 10.1039/D3SC04836E
Photocatalytic ethane conversion on rutile TiO2(110): identifying the role of the ethyl radical
Fangliang Li, Yuemiao Lai, Yi Zeng, Xiao Chen, Tao Wang, Qing Guo
DOI: 10.1039/D3SC05623F
A salt-concentrated electrolyte for aqueous ammonium-ion hybrid batteries
Jianming Meng, Jing Wang, Peng Hei, Chang Liu, Mengxue Li, Yulai Lin
DOI: 10.1039/D3SC05318K
A near-infrared light-activated nanoprobe for simultaneous detection of hydrogen polysulfide and sulfur dioxide in myocardial ischemia–reperfusion injury
Xianzhu Luo, Cuiling Zhang, Chenyang Yue, Yuelin Jiang, Fei Yang, Yuezhong Xian
DOI: 10.1039/D3SC04937J
Interface regulation of the Zn anode by using a low concentration electrolyte additive for aqueous Zn batteries
Kuo Wang, Qianrui Li, Guoli Zhang, Shuo Li, Tong Qiu
DOI: 10.1039/D3SC05098J
Convergent synthesis of thiodiazole dioxides from simple ketones and amines through an unusual nitrogen-migration mechanism
Kunlayanee Punjajom, Paul P. Sinclair, Ishika Saha, Mark Seierstad, Michael K. Ameriks, Pablo García-Reynaga, Terry P. Lebold, Richmond Sarpong
DOI: 10.1039/D3SC04478E
EnzymeMap: curation, validation and data-driven prediction of enzymatic reactions
Daniel Probst, William H. Green, Georg K. H. Madsen
DOI: 10.1039/D3SC02048G
Facile synthesis of 1,2-aminoalcohols via α-C–H aminoalkylation of alcohols by photoinduced hydrogen-atom transfer catalysis
Joaquim Caner, Akira Matsumoto
DOI: 10.1039/D3SC05305A
Atomically accurate site-specific ligand tailoring of highly acid- and alkali-resistant Ti(iv)-based metallamacrocycle for enhanced CO2 photoreduction
Yi-Qi Tian, Lin-Fang Dai, Wen-Lei Mu, Wei-Dong Yu, Jun Yan, Chao Liu
DOI: 10.1039/D3SC06046B
Advances in CO2 activation by frustrated Lewis pairs: from stoichiometric to catalytic reactions
Yara van Ingen, Tribani Boruah, Adam McLauchlan, Thomas Wirth, Rebecca L. Melen
DOI: 10.1039/D3SC03907B
You might also like
What precautions should be taken when handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3)?
When handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3), it ...
What precautions should be taken when handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9)?
When handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9), it...
How should waste containing 2-[2-(2-Methoxyethoxy)ethoxy]ethyl 4-methylbenzenesulfonate (CAS: 62921-74-8) be handled?
Waste containing this compound (CAS: 62921-74-8) should be handled according to ...
How should waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate be handled?
Waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate should be collected i...
How is 5-({4-[(2S,4R)-4-Hydroxy-2-methyltetrahydro-2H-pyran-4-yl]-2-thienyl}sulfanyl)-1-methyl-1,3-dihydro-2H-indol-2-one (CAS: 166882-70-8) typically synthesized?
This compound can be synthesized using a multi-step process involving the conjug...
Are there alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid (CAS: 7312-27-8) in synthesis?
There are several alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid in syn...
How should Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84-9) be stored?
Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84...
How should waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) be handled?
Waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) should be coll...
How is Methyl 5-iodo-2-methylbenzoate (CAS: 103440-54-6) typically synthesized?
Methyl 5-iodo-2-methylbenzoate can be synthesized through the iodination of meth...
How is 5-Chloro[1,2,4]triazolo[1,5-a]pyridine (CAS: 1427399-34-5) typically synthesized?
5-Chloro[1,2,4]triazolo[1,5-a]pyridine is commonly synthesized via the condensat...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.



![6-Benzyl-4,5,6,7-tetrahydro-1H-pyrazolo[3,4-c]pyridin-3(2H)-one structure 6-Benzyl-4,5,6,7-tetrahydro-1H-pyrazolo[3,4-c]pyridin-3(2H)-one structure](https://static.chemtradehub.com/structs/909/909187-64-0-f54f.webp)
