Spectroscopic characterisation of centropolyindanes

Literature Information

Publication Date 2019-02-04
DOI 10.1039/C8CP07311B
Impact Factor 3.676
Authors

Stewart F. Parker, Lisha Zhong, Marco Harig, Dietmar Kuck


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Abstract

A highly promising class of three-dimensional polyaromatic hydrocarbons comprises the centropolyindanes. The characteristic feature of these compounds is the mutual fusion of several molecules of indane along the saturated C–C bonds of their cyclopentane rings. Among the polycyclic aromatic hydrocarbons, the centropolyindanes are special because of the saturated core of sp3-hybridised carbon atoms embedded in a three-dimensional environment of aromatic building blocks. While the centropolyindanes and their numerous derivatives have been studied in detail by NMR spectroscopy, mass spectrometry and X-ray diffraction, investigation of their vibrational features, and especially those of the neopentane core present in most cases, have not been performed so far. In the present paper, we report the first systematic study of a set of centropolyindanes by vibrational spectroscopy, using inelastic neutron scattering (INS), infrared and Raman spectroscopies.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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