Carborane-based metal–organic frameworks as highly selective sorbents for CO2 over methane
Literature Information
Youn-Sang Bae, Omar K. Farha, Alexander M. Spokoyny, Chad A. Mirkin, Joseph T. Hupp, Randall Q. Snurr
Separation of CO2/CH4 mixtures was studied in carborane-based metal–organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO2 over CH4 (∼17) are obtained, especially in the material with open metal sites.
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