Carborane-based metal–organic frameworks as highly selective sorbents for CO2 over methane

Literature Information

Publication Date 2008-07-15
DOI 10.1039/B805785K
Impact Factor 6.222
Authors

Youn-Sang Bae, Omar K. Farha, Alexander M. Spokoyny, Chad A. Mirkin, Joseph T. Hupp, Randall Q. Snurr


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Abstract

Separation of CO2/CH4 mixtures was studied in carborane-based metal–organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO2 over CH4 (∼17) are obtained, especially in the material with open metal sites.

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