Chemoselective epoxidation of cholesterol derivatives on a surface-designed molecularly imprinted Ru–porphyrin catalyst

Literature Information

Publication Date 2018-05-02
DOI 10.1039/C8CC00896E
Impact Factor 6.222
Authors

Satoshi Muratsugu, Hiroshi Baba, Tatsuya Tanimoto, Kana Sawaguchi, Satoru Ikemoto, Masahiro Tasaki, Yosuke Terao


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Abstract

A new molecularly imprinted Ru–porphyrin complex catalyst on a SiO2 support was designed, prepared, and characterized in a step-by-step manner for the C5C6 epoxidation of cholesterol derivatives. High chemoselectivity for the C5C6 epoxidation of cholesterol derivatives without protecting the 3-position OH group and other oxidizable functional groups was achieved on the molecularly imprinted catalyst.

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