A facile method to construct a 2,4,9-triazaadamantane skeleton and synthesize nitramine derivatives
Literature Information
Publication Date
2017-06-13
DOI
10.1039/C7QO00357A
Impact Factor
5.281
Authors
Tianjiao Hou, Jian Zhang, Chenjiao Wang, Jun Luo
View Original
Abstract
An unusual protocol for a “one-pot” three-step reaction to build a 2,4,9-triazaadamantane skeleton from triallylcarbinol was developed. The design and execution of these tactics are described in detail. Then a novel high energy density compound 2,4,9-trinitro-2,4,9-triazaadamantane-7-yl nitrate was prepared and fully characterized. The results indicate that this compound exhibits high thermal stability and high density (1.840 g cm−3).
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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Molecular Formula:
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