![N-[2-(4-Hydroxyphenoxy)-4-nitrophenyl]methanesulfonamide structure](https://static.chemtradehub.com/structs/109/109032-22-6-7c88.webp "N-[2-(4-Hydroxyphenoxy)-4-nitrophenyl]methanesulfonamide structure")
N-[2-(4-Hydroxyphenoxy)-4-nitrophenyl]methanesulfonamide
CAS Number:
109032-22-6
Molecular Formula:
C13H12N2O6S
Unprecedented cucurbituril-based ternary host–guest supramolecular polymers mediated through included alkyl chains
Literature Information
Publication Date
2014-05-30
DOI
10.1039/C4PY00512K
Impact Factor
5.582
Authors
Nana Sun, Dongdong Qi, Jianzhuang Jiang
View Original
Abstract
Novel supramolecular polymers constructed from Q[8] and 1′,1′′-(alkylene-1,4-diyl)bis(1-butyl)-4,4′-(bipyridine-1,1′-diium)bromide (alkylene = hexylene, octylene) (1, 2) have been fabricated and characterized on the basis of a series of NMR, SEM, and DLS techniques. In particular, single crystal X-ray diffraction analysis clearly reveals their ternary host–guest construction nature by mediating the Q[8] host molecule through two terminal butyl chains (that are simultaneously included inside the host cavity) of two guest molecules depending on multiple hydrogen bonding interactions between the host and guest molecules as well as between the host and host molecules with the total energy amounting to as high as 161.2 kJ mol−1. This represents the first example of ternary host–guest supramolecular polymers that are mediated through alkyl chains instead of aromatic moieties included.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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Recommended Compounds
![1-[(4-Methylphenyl)sulfonyl]-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrolo[2,3-b]pyridine-5-carbonitrile structure](https://static.chemtradehub.com/structs/143/1434747-57-5-fc0d.webp "1-[(4-Methylphenyl)sulfonyl]-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrolo[2,3-b]pyridine-5-carbonitrile structure")
1-[(4-Methylphenyl)sulfonyl]-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrolo[2,3-b]pyridine-5-carbonitrile
CAS Number:
1434747-57-5
Molecular Formula:
C21H22BN3O4S
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