Side-chain engineering in naphthalenediimide-based n-type polymers for high-performance all-polymer photodetectors
Literature Information
Publication Date
2017-12-08
DOI
10.1039/C7PY01980G
Impact Factor
5.582
Authors
Wenqiang Qiao, Canglong Wang, Dongge Ma, Yuning Li
View Original
Abstract
A series of n-type semiconducting conjugated polymers based on naphthalene diimide (NDI) having three different side chains, 5-decylpentadecyl, 2-octyldodecyl and 4-(2-octyldodecyloxy)phenyl, were synthesized. Experimental results showed that the subtle structural changes at the side chains can influence the molecular packing, electron mobility, blend film morphology and thus performance of bulk-heterojunction polymer photodetectors using these NDI-based polymers as acceptors. The optimized all-polymer photodetector exhibited a specific detectivity (D*) of over 1013 Jones in the spectral region of 300–800 nm under −0.1 V bias, which is among the best D* values of the reported UV–vis–NIR all-polymer photodetectors and comparable to the best fullerene-based photodetectors.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
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Recommended Compounds
![5,10-Dihydroindeno[2,1-a]indene structure](https://static.chemtradehub.com/structs/654/6543-29-9-71ca.webp "5,10-Dihydroindeno[2,1-a]indene structure")
![Benzeneacetic acid, 2-bromo-α-[[(1,1-dimethylethoxy)carbonyl]amino]-, (αS)- structure](https://static.chemtradehub.com/structs/122/1228547-87-2-f296.webp "Benzeneacetic acid, 2-bromo-α-[[(1,1-dimethylethoxy)carbonyl]amino]-, (αS)- structure")
Benzeneacetic acid, 2-bromo-α-[[(1,1-dimethylethoxy)carbonyl]amino]-, (αS)-
CAS Number:
1228547-87-2
Molecular Formula:
C13H16BrNO4
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