Lanthanide complexes derived from (R)-1,1′-binaphthyl-2,2′-bis(neopentylamine) – {Li(THF)4}{Ln[(R)-C20H12N2(C10H22)]2} (Ln = Sm, Yb) – novel catalysts for enantioselective intramolecular hydroamination

Literature Information

Publication Date 2003-11-07
DOI 10.1039/B310954B
Impact Factor 6.222
Authors

Jacqueline Collin, Jean-Claude Daran, Emmanuelle Schulz, Alexander Trifonov


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Abstract

The complexes {Li(THF)4}{Ln[(R)-C20H12N2(C10H22)]2} (Ln = Sm, Yb) have been synthesized, fully characterized and found to be efficient and enantioselective catalysts for intramolecular hydroamination of 1-(aminomethyl)-1-allylcyclohexane.

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