Visible-light responsive hydrogen-bonded supramolecular polymers based on ortho-tetrafluorinated azobenzene
Literature Information
Publication Date
2017-11-13
DOI
10.1039/C7PY01612C
Impact Factor
5.582
Authors
Meng-Di Lin, Jie Wei, Li-Juan Liu, Meng-Yan Yun, Lin Wu, Si-Tai Zheng, Huan-Huan Yin, Li-Chun Kong
View Original
Abstract
Novel visible-light responsive hydrogen-bonded supramolecular polymers have been successfully constructed by using a linear molecule, which consists of two ureido-pyrimidinone (UPy) moieties connected by a photochromic ortho-tetrafluorinated azobenzene (TFAB) linker. Benefiting from the visible-light responsive feature of the TFAB unit, reversible photoisomerization between the two isomers of the monomer can be achieved. The E-isomer prefers to form a linear supramolecular polymer through the intermolecular quadruple hydrogen bonding interactions between UPys, whereas the Z-isomer facilely forms a cyclic dimer. Therefore, the polymerization mechanisms and properties of such supramolecular polymers, e.g. reversible visible-light induced gel–sol transformation behaviour, can be regulated by the reversible visible-light triggered E/Z photo-isomerization of the TFAB chromophore.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
3-(3-Ethyl-1-methyl-3-azepanyl)phenol hydrochloride (1:1)
CAS Number:
59263-76-2
Molecular Formula:
C15H24ClNO
Methyl 2-cyano-3,12-dioxooleana-1,9(11)-dien-28-oate
CAS Number:
218600-53-4
Molecular Formula:
C32H43NO4
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