Reversible C–C bond formation: solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium, and its solution state retro-aldol dissociation

Literature Information

Publication Date 2003-02-19
DOI 10.1039/B211745B
Impact Factor 6.222
Authors

Lee-Jon Ball, Anthony P. Dickie, Francis S. Mair, David A. Middleton, Robin G. Pritchard


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Abstract

Analysis of crystals of the lithium complex of the tripodal ligand formed upon addition of adamantanone to a 1,5 diazapentadienyllithium complex reveals a long C–C bond which ruptures upon dissolution in non-co-ordinating solvents.

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