Reversible C–C bond formation: solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium, and its solution state retro-aldol dissociation
Literature Information
Lee-Jon Ball, Anthony P. Dickie, Francis S. Mair, David A. Middleton, Robin G. Pritchard
Analysis of crystals of the lithium complex of the tripodal ligand formed upon addition of adamantanone to a 1,5 diazapentadienyllithium complex reveals a long C–C bond which ruptures upon dissolution in non-co-ordinating solvents.
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