Anionic triazacyclononanes: new supporting ligands in main group and transition metal organometallic chemistry
Literature Information
Joseph A. R. Schmidt, Garth R. Giesbrecht, Chunming Cui, John Arnold
In the course of developing new ligands to support chemistry with main-group, transition and lanthanide elements, a number of research groups have focused attention on functionalized triazacyclononanes; this article provides a summary of the more recent findings with an emphasis on the organometallic chemistry of one particular class of tacn ligands, namely those involving the anionic tacn moiety.
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![2-{[(1R,2S)-2-Aminocyclohexyl]amino}-4-{[3-(2H-1,2,3-triazol-2-yl)phenyl]amino}-5-pyrimidinecarboxamide structure 2-{[(1R,2S)-2-Aminocyclohexyl]amino}-4-{[3-(2H-1,2,3-triazol-2-yl)phenyl]amino}-5-pyrimidinecarboxamide structure](https://static.chemtradehub.com/structs/137/1370261-96-3-40df.webp)

