Sequence-coded ATRP macroinitiators

Literature Information

Publication Date 2017-04-07
DOI 10.1039/C7PY00496F
Impact Factor 5.582
Authors

Sofia Telitel, Benoît Éric Petit, Salomé Poyer, Laurence Charles, Jean-François Lutz


View Original

Abstract

Sequence-coded oligourethanes were tested as macroinitiators for the atom transfer radical polymerization (ATRP) of styrene. These oligomers were synthesized by solid-phase orthogonal iterative chemistry and transformed into ATRP initiators using a three-step modification procedure. A controlled radical polymerization behavior was observed with these macroinitiators, thus opening interesting opportunies for the synthesis of macromolecular architectures containing sequence-defined segments.

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Polymer Chemistry

Polymer Chemistry
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