An electrochemical perspective on the roles of ligands in the merger of transition-metal catalysis and electrochemistry

Literature Information

Publication Date 2020-12-28
DOI 10.1039/D0QO01227K
Impact Factor 5.281
Authors

Jun-Song Zhong, Yi Yu, Zhaojiang Shi, Ke-Yin Ye


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Abstract

The merger of transition-metal catalysis and electrochemistry has emerged as a very versatile and robust synthetic tool in organic synthesis. Like in their non-electrochemical variants, ligands also play crucial roles in fundamental reactions in transition-metal catalysis under electrochemical conditions. Herein, a perspective on the roles of ligands in transition-metal catalysis under electrochemical conditions is provided with selected transformations enabled by such a merger including C–H functionalization, difunctionalization of alkenes, cross-coupling reactions and carboxylation with CO2.

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Source Journal

Organic Chemistry Frontiers

Organic Chemistry Frontiers
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Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

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