Rhodium(iii)-catalyzed directed C–H benzylation and allylation of indoles with organosilicon reagents
Literature Information
Publication Date
2016-11-29
DOI
10.1039/C6QO00589F
Impact Factor
5.281
Authors
Ming-Zhu Lu, Cheng-Qiang Wang, Sheng-Jin Song
View Original
Abstract
Rhodium(III)-catalyzed C2-benzylation and allylation of indoles with organosilicon reagents via chelation-assisted C–H activation has been developed. This protocol demonstrates a board substrate scope, tolerates a broad range of synthetically useful functional groups, and enables a straightforward route to C2-benzyl- and allylindole derivatives.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
(1,3-Dimethyl-2,6-dioxo-1,2,3,6-tetrahydro-7H-purin-7-yl)acetaldehyde
CAS Number:
5614-53-9
Molecular Formula:
C9H10N4O3
![1-Oxa-8-azaspiro[4.5]decan-3-ol structure](https://static.chemtradehub.com/structs/757/757239-76-2-a0ec.webp "1-Oxa-8-azaspiro[4.5]decan-3-ol structure")
![2-[2-(2-Methoxyethoxy)ethoxy]-2-methylpropane structure](https://static.chemtradehub.com/structs/527/52788-79-1-71c1.webp "2-[2-(2-Methoxyethoxy)ethoxy]-2-methylpropane structure")
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