Cross-linked ROMP polymers based on odourless dicyclopentadiene derivatives
Literature Information
Publication Date
2016-04-14
DOI
10.1039/C6PY00378H
Impact Factor
5.582
Authors
Sukdeb Saha, Yakov Ginzburg, Illya Rozenberg, Olga Iliashevsky, Amos Ben-Asuly, N. Gabriel Lemcoff
View Original
Abstract
Hydroxydicyclopentadiene (DCPD-OH) and some ester and ether derivatives were synthesized and used for the first time as ring-opening metathesis polymerization (ROMP) monomers to create cross-linked thermoset polymers with Ru-catalysts. The properties of this new family of polymers were measured mainly by means of TGA, DSC and DMA to compare them with those of polydicylopentadiene (pDCPD). The novel polymers showed thermal properties comparable to those of pDCPD; although glass transition temperatures were mainly reduced by the modifications. More importantly, tuneable physical properties, depending on the substituents attached, were obtained. Thus, a window towards many important applications is opened by making novel thermoset ROMP homopolymers and copolymers from monomers with significantly reduced odour.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
1,3(2H,4H)-Isoquinolinedione, 7-amino-4,4-dimethyl-
CAS Number:
14576-22-8
Molecular Formula:
C11H12N2O2
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