Regiospecific and site-selective C–H allylation of phenols with vinyldiazo compounds catalyzed by In(iii)

Literature Information

Publication Date 2021-09-10
DOI 10.1039/D1QO01184G
Impact Factor 5.281
Authors

Dan Zhao, Jingyan Luo, Lu Liu


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Abstract

Metal-catalyzed C–H functionalization is one of the most effective methods to form a C–C bond. We herein report a highly regiospecific, site-selective, and C–H chemoselective substitution reaction of phenols with alkenyl diazo compounds catalyzed by commercially available and low-cost In(OTf)3. The reactions of aryl or alkyl substituted vinyldiazoacetates provided the corresponding phenol-allylation products in different regioselective and site-selective manners.

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Organic Chemistry Frontiers

Organic Chemistry Frontiers
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Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

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