Regiospecific and site-selective C–H allylation of phenols with vinyldiazo compounds catalyzed by In(iii)
Literature Information
Publication Date
2021-09-10
DOI
10.1039/D1QO01184G
Impact Factor
5.281
Authors
Dan Zhao, Jingyan Luo, Lu Liu
View Original
Abstract
Metal-catalyzed C–H functionalization is one of the most effective methods to form a C–C bond. We herein report a highly regiospecific, site-selective, and C–H chemoselective substitution reaction of phenols with alkenyl diazo compounds catalyzed by commercially available and low-cost In(OTf)3. The reactions of aryl or alkyl substituted vinyldiazoacetates provided the corresponding phenol-allylation products in different regioselective and site-selective manners.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
![N-[2-(4-Hydroxyphenoxy)-4-nitrophenyl]methanesulfonamide structure](https://static.chemtradehub.com/structs/109/109032-22-6-7c88.webp "N-[2-(4-Hydroxyphenoxy)-4-nitrophenyl]methanesulfonamide structure")
N-[2-(4-Hydroxyphenoxy)-4-nitrophenyl]methanesulfonamide
CAS Number:
109032-22-6
Molecular Formula:
C13H12N2O6S
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