The radical acylarylation of N-arylacrylamides with aliphatic aldehydes using the photolysis of hypervalent iodine(iii) reagents

Literature Information

Publication Date 2018-07-14
DOI 10.1039/C8OB01420E
Impact Factor 3.876
Authors

Ryu Sakamoto, Naomichi Hirama


View Original

Abstract

This article describes a variety of 3,3-disubstituted 2-oxindoles that bear carbonyl groups, which are efficiently obtained from a radical reaction between N-arylacrylamides and aliphatic aldehydes. The reaction is initiated by the photolysis of hypervalent iodine(III) reagents and proceeds smoothly under mild, metal-free conditions.

Related Literature

Exciton transfer free energy from Car–Parrinello molecular dynamics

Christian Schwermann, Nikos L. Doltsinis

2020-01-16 Paper

DOI: 10.1039/C9CP06419B

Inside front cover

Cover

DOI: 10.1039/D0CP90115F

Wetting state transition of a liquid gallium drop at the nanoscale

Meng Yan, Tao Li, Peiru Zheng, Rubin Wei, Yanyan Jiang, Hui Li

2020-04-21 Paper

DOI: 10.1039/D0CP00985G

A vibrational spectroscopic and computational study of gaseous protonated and alkali metal cationized G–C base pairs

Ruodi Cheng, Jonathan Martens, Travis D. Fridgen

2020-05-04 Paper

DOI: 10.1039/D0CP00069H

Effect of zeolite morphology on charge separated states: ZSM-5-type nanocrystals, nanosheets and nanosponges

Lucie Duplouy, Alain Moissette, Matthieu Hureau, Vincent De Waele, Isabelle Batonneau-Gener

2020-05-07 Paper

DOI: 10.1039/D0CP01701A

X-ray photoelectron spectroscopy of piperidinium ionic liquids: a comparison to the charge delocalised pyridinium analogues

Peter Licence, Chi-Linh Do-Thanh, Huimin Luo, Sheng Dai

2020-05-06 Paper

DOI: 10.1039/D0CP01454K

Solvent similarity index

Mark D. Driver, Christopher A. Hunter

2020-05-15 Paper

DOI: 10.1039/D0CP01570A

Inside front cover

Cover

DOI: 10.1039/D0CP90125C

Visualising electrochemical reaction layers: mediated vs. direct oxidation

Junling Ma, Minjun Yang, Christopher Batchelor-McAuley, Richard G. Compton

2020-05-22 Paper

DOI: 10.1039/D0CP01904F

Polyamines stimulate RecA-mediated recombination by condensing duplex DNA and stabilizing intermediates

Naciye Esma Tirtom, Yang Hsu, Hung-Wen Li

2020-05-14 Paper

DOI: 10.1039/D0CP01061H

You might also like

Compound Q&A

What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?

4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...

333338-18-44-Nitrophenyl phosph...
Compound Q&A

What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?

2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...

1060816-01-42-(Trifluoromethyl)-...
Compound Q&A

How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?

2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...

137045-30-82-Fluoro-4-biphenylc...
Compound Q&A

What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?

Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...

61549-70-0Prednisolone-21-Carb...
Compound Q&A

How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?

4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...

3614-72-04-(Hydrazinomethyl)-...
Compound Q&A

What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?

4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...

92534-70-84-Amino-1-methyl-1H-...
Compound Q&A

What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?

Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...

77012-31-8Dehydropachymic acid
Compound Q&A

What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?

The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...

898561-66-56-[(2,2-Dimethylprop...
Compound Q&A

How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?

1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...

57709-62-31,10-Phenanthroline-...
Compound Q&A

How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?

5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...

113952-21-95-Carbamoyl-11-oxo-1...

Source Journal

Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry
CiteScore: 3.4
Self-citation Rate: 10.3%
Articles per Year: 1041

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.