Should “anion–π interactions” be called “anion–σ interactions”? A revision of the origin of some hole-bonds and their nomenclature

Literature Information

Publication Date 2016-10-12
DOI 10.1039/C6CP06416G
Impact Factor 3.676
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Abstract

The so-called anion–π interactions are dissected to test if indeed the π system of the aromatic ring is the reason for the bond. In contrast, due to σ–holes the σ system is found to be responsible for a “pseudo-π hole” interaction. Models that form genuine anion–π bonds are discussed.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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